ICS 13.040.01 Z 25 山 DB37 东 省 地 方 标 准 DB 37/T 3459—2018 山东省固定污染源废气 颗粒物中铜、锌的 测定 电感耦合等离子体质谱法 Stationary source emission of Shandong - Determination of copper and zinc in ambient particulate matter-Inductively coupled plasma/mass spectrometry 2018 - 12 - 29 发布 山东省市场监督管理局 2019 - 01 - 29 实施 发 布 DB37/T 3459—2018 目  次 前言................................................................................................................................................................... III 1 范围................................................................................................................................................................... 1 2 规范性引用文件............................................................................................................................................... 1 3 方法原理........................................................................................................................................................... 1 4 干扰和消除....................................................................................................................................................... 1 4.1 质谱型干扰............................................................................................................................................... 1 4.2 非质谱型干扰........................................................................................................................................... 1 5 试剂和材料....................................................................................................................................................... 2 6 仪器和设备....................................................................................................................................................... 2 6.1 6.2 6.3 6.4 6.5 6.6 6.7 6.8 6.9 电感耦合等离子体质谱仪....................................................................................................................... 2 无组织排放废气采样设备....................................................................................................................... 2 烟尘采样器............................................................................................................................................... 3 微波消解仪............................................................................................................................................... 3 可调温电热板........................................................................................................................................... 3 全自动消解仪........................................................................................................................................... 3 剪刀........................................................................................................................................................... 3 镊子........................................................................................................................................................... 3 其他........................................................................................................................................................... 3 7 样品................................................................................................................................................................... 3 7.1 7.2 7.3 7.4 7.5 样品的采集............................................................................................................................................... 3 现场空白................................................................................................................................................... 3 样品的保存............................................................................................................................................... 3 试样的制备............................................................................................................................................... 3 实验室样品空白的制备........................................................................................................................... 5 8 分析步骤........................................................................................................................................................... 5 8.1 8.2 8.3 8.4 仪器调谐................................................................................................................................................... 5 校准曲线绘制................................................................